The Tesoro refinery in Martinez, California, for years ignored safety problems and fostered a weak safety culture, the United States Chemical Safety Board says in a report released on 2 August 2016. Board officials urged Tesoro and other refiners to elevate the importance of process safety and encouraged state and local regulators to frequently conduct preventive safety inspections of the facility. Triggering CSBs report and investigation were incidents in February and March 2014 at the facilitys alkylation unit, which carries out a process common at U.S. refineries. Tesoros unit uses sulfuric acid as a catalyst to reformulate low-value hydrocarbons, such as propane and butane, to produce a premium, high-octane gasoline blend stock. The first of the two accidents was the result of a piping failure that released some 38,000 kg of sulfuric acid over two hours and burned two employees. Tesoro initially characterised the accident as minor and refused to allow CSB to investigate. In the second incident a month later, two contract workers were sprayed and burned with sulfuric acid at the same unit. The two incidents followed 13 similar sulfuric acid accidents at the facility since 2010, CSB says. It suggests the company failed to learn from past mistakes and allowed accidents to continue. The second incident, CSB notes, had similarities to a 1999 incident at the refinery in which four workers were killed. Much of CSBs report focuses on the February 2014 accident which occurred in piping for the plants sulfuric acid sampling system. Tesoro had purchased and intended to install a new, closed-loop, so-called inherently safer acid sampling system that is similar to those used at other California refineries. However, the company claimed the system was unreliable, CSB says, and never installed it. Instead Tesoro slightly upgraded its existing sampling system, which requires workers who draw samples to wear personal protective gear to counter the expected release of sulfuric acid vapours. Tesoro officials would not comment on the specific accident or decision not to install inherently safer technology. They, however, cited unspecified inaccuracies in CSBs report.
Chemical & Engineering News, 4 August 2016 ;http://pubs.acs.org/cen/news ;